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AAg2PS4 (A = K, Na/K): the first-type of noncentrosymmetric alkali metal Ag-based thiophosphates exhibiting excellent second-order nonlinear optical performances

Authors :
Wenfeng Zhou
Bingxuan Li
Wenlong Liu
Sheng-Ping Guo
Source :
Inorganic Chemistry Frontiers. 9:4990-4998
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

The first-type of NCS alkali metal Ag-based thiophosphates KAg2PS4 (1) and (Na0.30K0.70)Ag2PS4 (2) exhibit large SHG responses, originating from the ordered arrangement of AgS4 and PS4 tetrahedra, and high LIDTs contributed by alkali metals.

Subjects

Subjects :
Inorganic Chemistry

Details

ISSN :
20521553
Volume :
9
Database :
OpenAIRE
Journal :
Inorganic Chemistry Frontiers
Accession number :
edsair.doi...........bdc38ea1227871c2bdeab170c2f27dbb
Full Text :
https://doi.org/10.1039/d2qi01292h