ChemInform Abstract: Synthesis and Reactions of Monosilylated 1,3,5-Hexatriyne and 1,3,5,7- Octatetrayne. Total Synthesis of Caryoynencins

Authors :: Tetsuo Hiraoka
Hiroshi Nishihara
Shigeo Nakamura
Hyeon-Joo Park
Kazuhiko Torisu
Masahiko Yamaguchi
Toru Minami
Masahiro Hirama
Source :: ChemInform. 25
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: Selective monodesilylation of 1,8-bis(t-butyldiphenylsilyl)-1,3,5,7-octatetrayne and 1,6-bis(t-butyldiphenylsilyl)-1,3,5-hexatriyne with lithiated phenylacetylene gave unstable 1-(t-butyldiphenylsi...

Subjects :: chemistry.chemical_compound
Phenylacetylene
chemistry
Organic chemistry
Total synthesis
General Medicine

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