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The Nature of P(σ2λ3↔σ2λ1) Dualism: 3a,6a-Diaza-1,4-diphosphapentalene as a Form of Stabilized Singlet Phosphinidene

Authors :
Diego F. Dorado Daza
Anton V. Cherkasov
Alexander S. Novikov
Gleb A. Abakumov
Vyacheslav V. Sushev
Alexander N. Kornev
Yulia S. Panova
Georgy K. Fukin
Source :
Inorganic Chemistry. 58:16144-16153
Publication Year :
2019
Publisher :
American Chemical Society (ACS), 2019.

Abstract

The current study provides a clear understanding of the chemical properties of annelated 3a,6a-diaza-1,4-diphosphapentalenes (DDPs), which are best viewed as stabilized singlet phosphinidenes. It w...

Details

ISSN :
1520510X and 00201669
Volume :
58
Database :
OpenAIRE
Journal :
Inorganic Chemistry
Accession number :
edsair.doi...........beca42715a8b1ce0dea9528196c6ac45
Full Text :
https://doi.org/10.1021/acs.inorgchem.9b02690