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Potential of Molecular Nitrogen Fixation by Carbonyl Clusters of Platinum Metals in Lower Oxidation States: A Review

Potential of Molecular Nitrogen Fixation by Carbonyl Clusters of Platinum Metals in Lower Oxidation States: A Review

Authors :
I. V. Fedoseev
Andrei V. Shevelkov
V. V. Vasekin
Source :
Russian Journal of Inorganic Chemistry. 66:1275-1282
Publication Year :
2021
Publisher :
Pleiades Publishing Ltd, 2021.

Abstract

This minireview presents the results that show the potential of molecular nitrogen fixation by carbonyl cluster compounds of platinum metals at room temperature and atmospheric pressure to produce ammonia or its derivatives. Although the main attention is given to processes with the participation of derivatives of platinum and palladium, it was demonstrated that molecular nitrogen fixation is characteristic of all the platinum metals, except osmium.

Details

ISSN :
15318613 and 00360236
Volume :
66
Database :
OpenAIRE
Journal :
Russian Journal of Inorganic Chemistry
Accession number :
edsair.doi...........bf855dae441d745ea3f90dec20b067a2
Full Text :
https://doi.org/10.1134/s0036023621090023