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[Untitled]

Authors :
Evgeny V. Votyakov
Yu. K. Tovbin
Source :
Russian Chemical Bulletin. 50:50-59
Publication Year :
2001
Publisher :
Springer Science and Business Media LLC, 2001.

Abstract

The phase diagrams describing condensation of adsorbate in micro- and mesoporous adsorbents having slit-shaped and cylindrical pores whose size varied from 1 to 20 monolayers were constructed. The study was performed using the lattice-gas model in the quasichemical approximation to take into account the intermolecular interactions. The phase diagrams for various values of the potential arising from different types of adsorbate--adsorbent interaction were analyzed for adsorption of helium, neon, methane, and carbon tetrachloride in graphite pores. Other adsorption systems are considered and the relationship between the pressure and temperature of adsorbate condensation is discussed. A nonmonotonic variation of the critical densities for pore widths from 3 to 10 molecular diameters was found. The pattern of this variation depends on the ratio of the energy of lateral interactions of the adsorbate molecules to the energy of interaction of the adsorbate molecules with pore walls. The critical temperature decreases monotonically with a decrease in the pore width. The stronger the adsorbate interaction with the pore walls, the greater the decrease in the critical temperature.

Details

ISSN :
10665285
Volume :
50
Database :
OpenAIRE
Journal :
Russian Chemical Bulletin
Accession number :
edsair.doi...........bfe066797c8840afa4c97e3feb9a8795
Full Text :
https://doi.org/10.1023/a:1009516932722