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[Untitled]
- Source :
- Russian Chemical Bulletin. 50:50-59
- Publication Year :
- 2001
- Publisher :
- Springer Science and Business Media LLC, 2001.
-
Abstract
- The phase diagrams describing condensation of adsorbate in micro- and mesoporous adsorbents having slit-shaped and cylindrical pores whose size varied from 1 to 20 monolayers were constructed. The study was performed using the lattice-gas model in the quasichemical approximation to take into account the intermolecular interactions. The phase diagrams for various values of the potential arising from different types of adsorbate--adsorbent interaction were analyzed for adsorption of helium, neon, methane, and carbon tetrachloride in graphite pores. Other adsorption systems are considered and the relationship between the pressure and temperature of adsorbate condensation is discussed. A nonmonotonic variation of the critical densities for pore widths from 3 to 10 molecular diameters was found. The pattern of this variation depends on the ratio of the energy of lateral interactions of the adsorbate molecules to the energy of interaction of the adsorbate molecules with pore walls. The critical temperature decreases monotonically with a decrease in the pore width. The stronger the adsorbate interaction with the pore walls, the greater the decrease in the critical temperature.
- Subjects :
- Condensation
Intermolecular force
chemistry.chemical_element
Langmuir adsorption model
General Chemistry
Condensed Matter::Soft Condensed Matter
Condensed Matter::Materials Science
Neon
symbols.namesake
Adsorption
chemistry
Chemisorption
Chemical physics
symbols
Physical chemistry
Physics::Chemical Physics
Mesoporous material
Phase diagram
Subjects
Details
- ISSN :
- 10665285
- Volume :
- 50
- Database :
- OpenAIRE
- Journal :
- Russian Chemical Bulletin
- Accession number :
- edsair.doi...........bfe066797c8840afa4c97e3feb9a8795
- Full Text :
- https://doi.org/10.1023/a:1009516932722