Back to Search
Start Over
Photoinduced and thermal reactions of molecular σ radical cations of some branched alkanes in low-temperature matrices: An ESR study
- Source :
- Chemical Physics Letters. 105:414-419
- Publication Year :
- 1984
- Publisher :
- Elsevier BV, 1984.
-
Abstract
- The photoinduced and thermal reactions of σ radical cations of methyl-substituted propanes and butanes in the condensed phases have been characterized by ESR. Photoelimination of CH4 giving olefinic π radical cations commonly takes place except for H2 elimination from isobutane radical cations. The thermal reactions of methyl-substituted butane radical cations in CFCl2CF2Cl were found to be deprotonation from the CH3 group to give primary alkyl radicals.
Details
- ISSN :
- 00092614
- Volume :
- 105
- Database :
- OpenAIRE
- Journal :
- Chemical Physics Letters
- Accession number :
- edsair.doi...........c27f4ecb56dd7ff7423ec1c6c8fab472