ChemInform Abstract: Thiacrown Ether as Regulator of Lipase-Catalyzed trans-Esterification in Organic Media: Practical Optical Resolution of Allyl Alcohols

Authors :: Hiroshi Kihara
Toshiyuki Itoh
Jun Teramoto
Yumiko Takagi
Hiroshi Tsukube
Source :: ChemInform. 27
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: Thiacrown ether additive enhanced enantioselectivity in lipase-catalyzed trans-esterification of allyl alcohols. Small amounts of thiacrown ether offered highly enantioselective reaction when 5-phenylpentene-3-ol was subjected to the reaction of Pseudomonas cepacia lipase.

Subjects :: Resolution (mass spectrometry)
biology
Pseudomonas
Enantioselective synthesis
Ether
General Medicine
Trans esterification
biology.organism_classification
Organic media
Catalysis
chemistry.chemical_compound
chemistry
biology.protein
Organic chemistry
Lipase

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