Correlation between precipitates evolution and mechanical properties of Al-Sc-Zr alloy with Er additions

Correlation between precipitates evolution and mechanical properties of Al-Sc-Zr alloy with Er additions during isothermal ageing were investigated by microhardness measurements, transmission electron microscopy, atom probe tomography and density functional theory-based simulations. The results demonstrate that the Er additions significantly improve the hardness during elevated temperature ageing, especially at 400°C. This is mainly because Er additions increase the nucleation rate of the Al3(Er,Sc,Zr) precipitates, resulting in a higher density of fine and uniform dispersion of L12 structured nanoparticles. First-principles calculations demonstrate that the second nearest neighboring solute-solute interactions for the species Sc, Zr and Er are energetically favored – a key feature to rationalize the observed precipitate structure and the underlying formation mechanism. The sequential formation of the core/shell precipitates in the Er-free alloy and core/double-shell precipitates in the Er-containing alloy arises due to the different solute-solute and solute-vacancy interaction energies, and the relative diffusivities of the Er, Sc and Zr species in Al. These results shed light on the beneficial effects of Er additions on the age-hardening behavior of Al-Sc-Zr alloy and provide guidance for designing the ageing treatments for the Al-Sc-Zr(-Er) alloys.