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First synthesis of α-fluorinated cyclopropylphosphonates using magnesium electrochemical activation

Authors :
Sophie Goumain
Philippe Jubault
Jean-Charles Quirion
Christian Feasson
Source :
Tetrahedron Letters. 40:8099-8101
Publication Year :
1999
Publisher :
Elsevier BV, 1999.

Abstract

The synthesis of α-fluorinated cyclopropylphosphonates is efficiently achieved for the first time by electroreduction of diisopropyl dibromofluoromethylphosphonate in the presence of Michael acceptors in a one-compartment cell equipped with a magnesium sacrificial anode.

Details

ISSN :
00404039
Volume :
40
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........c93a05cf030bbd0cc091eed363b5ea97
Full Text :
https://doi.org/10.1016/s0040-4039(99)01698-6