Evolution of the North West Arm and the Central Sector of Mashava Igneous Complex in south central Zimbabwe from an investigation of its silicate minerals compositions

An investigation of the economically important Mashava Igneous Complex (MIC) in Zimbabwe was conducted using petrographic and silicate mineral compositions to gain some insights into its origin. The MIC, an ultramafic-mafic complex located in the western extremity of the Masvingo greenstone belt (MGSB), is composed of amphibole, serpentine, epidote, chlorite, clinopyroxene, orthopyroxene, plagioclase, and olivine. Spinel, sulfide minerals, and minor quartz as well as other opaque minerals are also present. The dominant mineral is serpentine, which displays a wide range in both FeO and SiO2 compositions, and the majority of this mineral belongs to the lizardite, chrysotile, and antigorite varieties. Amphiboles display a wide range in composition from tremolite and actinolite which are both consistent with greenschist facies metamorphism, through magnesiohornblende to tschermakite which are both consistent with amphibolite facies metamorphism. Clinozoisite is the only epidote type occurring in the MIC, whereas chlorite varies widely in composition which reflects the varying concentrations in iron and silica in this mineral. Chlorite types range from talc chlorite through penninite, diabantite, pycnochlorite, brunsvigite, ripidolite, and pseudothuringite. Plagioclase shows a wide compositional range from high albite to bytownite, with only two samples plotting in the alkali feldspar anorthoclase field. Pyroxene ranges in composition from enstatite through pigeonite and augite to diopside whereas olivine is rich in MgO with forsterite contents ranging from 80 to 89. Application of the chlorite geothermometry equation of Kranidiotis and MacLean (1987) yields temperatures ranging from ∼200–320 °C whereas temperatures ranging from 130 to 445 °C are obtained using equations of Lanari et al. (2014) for the formation of this mineral, generally consistent with low- to medium-grade metamorphic conditions. Chlorites in the North West Arm were formed at relatively lower temperatures (97–234 °C) than those at which chlorites in the Central Sector were formed (204–445 °C). Pressure estimates for the metamorphism of the MIC range from 3.8 to 7.3 kbars, which corresponds to depths of ∼13–25 km, respectively. Based on the different silicate mineral compositions of the North West Arm and the Central Sector, it is inferred that these two blocks underwent different petrogenetic and evolutionary histories but they were later juxtaposed, possibly during thrusting of the former onto its present position.