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Novel aromatic oxy-Cope rearrangement. Participation of a benzene ring and intramolecular potassium-ion detachment by methoxy groups

Authors :
Masamori Tooya
Tadao Uyehara
Masako Ueno
Katsura Seki
Toshio Sato
Source :
Tetrahedron Letters. 39:8673-8676
Publication Year :
1998
Publisher :
Elsevier BV, 1998.

Abstract

The aromatic oxy-Cope rearrangement including a benzene ring took place when 1-methoxy-2-aryl-bicyclo[2.2.2]oct-5-en-2- exo -ols and 2-(2-methoxyphenyl)-bicyclo[2.2.2]oct-5-en- exo -2-ols were treated with KH in THF.

Details

ISSN :
00404039
Volume :
39
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........c9a79a546db17e0855163f03b64e3db5