Back to Search
Start Over
[Untitled]
- Source :
- Journal of Chemical Crystallography. 31:173-177
- Publication Year :
- 2001
- Publisher :
- Springer Science and Business Media LLC, 2001.
-
Abstract
- The structure of complex [PyH][Ni(mnt)2], as determined by X-ray single crystal analysis, consists of pyridinium cations and [Ni(mnt)2]− anions. Crystallographic data for the complex: monoclinic P21/c, a = 16.5430(18) A, b = 6.3847(9) A, c = 17.430(2) A, β = 118.040(7)°, V = 1625.4(3) A3, Z = 4. The [Ni(mnt)2]− anion is not a planar and the CN groups bend away from the S4 plane. The interactions between anions and cations via the formation of bifurcated N–H···N≡C hydrogen bonds give rise to an 1D zigzag chain of alternating cations and anions.
Details
- ISSN :
- 10741542
- Volume :
- 31
- Database :
- OpenAIRE
- Journal :
- Journal of Chemical Crystallography
- Accession number :
- edsair.doi...........cb90b01621de294d00512663d360d411