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Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon

Authors :
Thomas C. Hansen
Michael Marek Koza
Peter Fouquet
Emanuel Bahn
Stéphanie Pouget
Irene Calvo-Almazán
Alain Lapp
Vitalii Kuznetsov
Paul F. Henry
Mohamed Zbiri
Monica Mesa
Leidy A. Hoyos Giraldo
Source :
Carbon. 166:307-315
Publication Year :
2020
Publisher :
Elsevier BV, 2020.

Abstract

The diffusional behaviour of H2 adsorbed in a novel mesoporous N-doped carbon material and on exfoliated graphite has been studied with quasi-elastic neutron scattering. While the activation energies for diffusion obtained for exfoliated graphite was in line with prior results, H2 in the mesoporous carbon showed an exceptionally low diffusion barrier and behaved qualitatively like liquid hydrogen. Complementary results from neutron and X-ray diffraction as well as from isothermal nitrogen sorption studies provide a full characterisation of this novel mesoporous carbon.

Details

ISSN :
00086223
Volume :
166
Database :
OpenAIRE
Journal :
Carbon
Accession number :
edsair.doi...........cc46af6ff5b8fb1a0ea3815c87359b1c
Full Text :
https://doi.org/10.1016/j.carbon.2020.05.004