Asymmetric Electrophilic Amination and Hydrazination of Acyclic α-Branched Ketones for the Formation of α-Tertiary Amines and Hydrazines

Authors :: Jacob S. Tracy
Barry M. Trost
Eric Y. Lin
Source :: ACS Catalysis. 9:11082-11087
Publication Year :: 2019
Publisher :: American Chemical Society (ACS), 2019.
Abstract: Chiral α-tertiary amines can be accessed directly through the electrophilic amination of α-branched ketones utilizing di-tert-butyl azodicarboxylate as the electrophilic nitrogen source. This proce...

Subjects :: 010405 organic chemistry
Chemistry
Electrophilic amination
Electrophile
Organic chemistry
General Chemistry
010402 general chemistry
Nitrogen source
01 natural sciences
Catalysis
0104 chemical sciences

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