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A Rapid and Convenient Synthesis of Homoallylic Alcohols by the Barbier‐Grignard Reaction
- Source :
- Synthetic Communications. 34:3473-3480
- Publication Year :
- 2004
- Publisher :
- Informa UK Limited, 2004.
-
Abstract
- The use of the Barbier‐Grignard reaction, where premixed allyl bromide and the carbonyl compound are added to magnesium in ether, is reported for the synthesis of homoallylic alcohols. This reaction provides good to excellent yields of most homoallylic alcohols with minimal formation of Wurtz coupling products.
Details
- ISSN :
- 15322432 and 00397911
- Volume :
- 34
- Database :
- OpenAIRE
- Journal :
- Synthetic Communications
- Accession number :
- edsair.doi...........cf4420ddd089810f5ce84c0ed3af71da