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ChemInform Abstract: Synthesis of Enantiomerically Pure Bicyclic Condensed δ-Lactones via Microbial Reduction and Enzymic Resolution Strategies

Authors :
Patrizia Nitti
Erica Fogal
Cristina Forzato
Ennio Valentin
Giuliana Pitacco
Source :
ChemInform. 31
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

The formation of enantiopure δ-lactones condensed with alicyclic rings has been achieved either by reduction with baker's yeast of the corresponding δ-keto esters and δ-keto acids or by enzymic resolution of the former compounds. The absolute configurations of the lactones were determined by means of CD spectroscopy, using the correlation method.

Details

ISSN :
15222667 and 09317597
Volume :
31
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........d012f5a2476ed68e3b6035068dcacdec
Full Text :
https://doi.org/10.1002/chin.200046024