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A highly selective visual and fluorescent sensor for Pb2+ and Zn2+ and crystal structure of Cu2+ complex based-on a novel single-armed Salamo-type bisoxime
- Source :
- Supramolecular Chemistry. 29:518-527
- Publication Year :
- 2017
- Publisher :
- Informa UK Limited, 2017.
-
Abstract
- A novel single-armed Salamo-type bisoximes (H4L) has been designed and synthesised. An obvious colour change from yellow (H4L) to pale pink (HL-Pb2+) which can be visually observed by the naked eye in visible light. H4L can act as a fluorescent sensor for ratiometric recognition of Zn2+ with high selectivity and sensitivity. Crystallographic data of the [Cu(HL)(μ-OAc)Cu] reveals that the two Cu2+ ions are both penta-coordinated with square pyramidal geometries, and forms a 2D supramolecular plane structure by hydrogen bonding interactions.
Details
- ISSN :
- 10290478 and 10610278
- Volume :
- 29
- Database :
- OpenAIRE
- Journal :
- Supramolecular Chemistry
- Accession number :
- edsair.doi...........d01b3d810441db193d8b12a1d64203e3