Back to Search Start Over

Optical investigation of the thermoelectric topological crystalline insulatorPb0.77Sn0.23Se

Authors :
R. J. Cava
Anjan Reijnders
Jason Hamilton
Quinn Gibson
Pascale Roy
Kenneth S. Burch
Vivian Britto
Jean-Blaise Brubach
Source :
Physical Review B. 90
Publication Year :
2014
Publisher :
American Physical Society (APS), 2014.

Abstract

${\mathrm{Pb}}_{0.77}{\mathrm{Sn}}_{0.23}\mathrm{Se}$ is a promising thermoelectric alloy that exhibits a temperature dependent band inversion below 300 K. Recent work has shown that this band inversion also coincides with a trivial to nontrivial topological phase transition. To understand how the properties critical to thermoelectric efficiency are affected by the band inversion, we measured the broadband optical response of ${\mathrm{Pb}}_{0.77}{\mathrm{Sn}}_{0.23}\mathrm{Se}$ as a function of temperature. We find clear optical signatures suggesting the band inversion occurs at $160\ifmmode\pm\else\textpm\fi{}15$ K, and use the extended Drude model to accurately determine a ${T}^{3/2}$ dependence of the bulk carrier lifetime, associated with electron-acoustic phonon scattering. Due to the high bulk carrier doping level, no discriminating signatures of the topological surface states are found, although their presence cannot be excluded from our data.

Details

ISSN :
1550235X and 10980121
Volume :
90
Database :
OpenAIRE
Journal :
Physical Review B
Accession number :
edsair.doi...........d0fbb87fef053b04a4d5d6824feb7da4
Full Text :
https://doi.org/10.1103/physrevb.90.235144