Assessment of arsenic and uranium co-occurrences in groundwater of central Gangetic Plain, Uttar Pradesh, India

Arsenic and uranium in the aquatic environment are recognized as a major catastrophic problem worldwide and have natural as well as human-made sources such as mining, industry and agriculture. The severity of this problem is further accelerated by in-situ physio-chemical factors in the fluvial environment which enhances the concentration of arsenic and uranium in groundwater that feeds millions of people in Central Gangetic Plain in India. This study aims to establish a better understanding of the processes responsible for the co-occurrence of arsenic and uranium along with the factors controlling their solubility and mobility in the groundwater of central Gangetic plain. This study is an attempt to bring out the (a) the spatial distribution pattern of arsenic and uranium, (b) insight into the hydrogeochemical characteristics of aquifers that are controlling their co-occurrence and provides (c) information of their source which are validated by statistical tools. Silicate weathering controls U mobilization and distribution whereas carbonate dissolution and ion exchange process controls As in groundwater. The land use and land cover pattern of the North-eastern (NE) part of the study area is agriculture dominated and is composed of Holocene older alluvium. However, the South and South-western areas which are closer to the river are formed by the deposition of river born newer alluvial. Newer alluvium in the SW part has unoxidized organic-rich clay that enhances arsenic mobilization by reductive dissolution of Fe-oxyhydroxide. In the NE region, the abundance of fertilizers in the subsurface oxidizing environment augments the solubility and mobility of uranium.