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The stable lithium metal cell with two-electrode biomass carbon

Authors :
Jun Yan
Yinyi Gao
Dianxue Cao
Pengfei Wang
Zhe Gong
Ke Ye
Kai Zhu
Guiling Wang
Source :
Electrochimica Acta. 356:136824
Publication Year :
2020
Publisher :
Elsevier BV, 2020.

Abstract

As a mainstream energy storage device, lithium-ion batteries have always been the focus of scientific researchers. As the most promising anode material, lithium metal has the advantages of high capacity and low reduction potential. Unfortunately, lithium dendrites can cause serious safety hazards during cycling. In this study, biomass carbon with a large number of straight holes was embedded with nickel particles as the anode framework. Nickel induces lithium to complete nucleation and growth in the pores and inhibits dendrite growth. Solid electrolyte interface (SEI) film growth, dead lithium, and electrode breakage all occur within the holes to a limited extent. Benefited from this internal reaction, the electrode obtains better electrochemical and cycling performances. The nickel-modified electrode was stably cycled for 1370 h at a current density of 5 mA/cm2 with a capacity of 2 mAh/cm2. Moreover, more massive capacity lithium storage (5 mAh/cm2) was tried, and the cycle was stable for 630 h. Using the same biomass carbon matrix, the pores were filled with sulfur powder as the positive electrode. After 100 periods of the full cell operation, the capacity retention rate is 85%.

Details

ISSN :
00134686
Volume :
356
Database :
OpenAIRE
Journal :
Electrochimica Acta
Accession number :
edsair.doi...........d21832e3c666862b248eee7085d72e82
Full Text :
https://doi.org/10.1016/j.electacta.2020.136824