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An Enamine/HB(C6F5)2 Adduct as a Dormant State in Frustrated Lewis Pair Chemistry

Authors :
Kathrin Bussmann
Constantin G. Daniliuc
Gerald Kehr
Stefan Grimme
Jan Gerit Brandenburg
Roland Fröhlich
Gerhard Erker
Bao-Hua Xu
Source :
Organometallics. 32:6745-6752
Publication Year :
2013
Publisher :
American Chemical Society (ACS), 2013.

Abstract

The enamine piperidinocyclopentene reacts with HB(C6F5)2 by formation of the C-Lewis base/B-Lewis acid adduct 10. It shows a zwitterionic iminium ion/hydridoborate structure. However, this adduct f...

Subjects

Subjects :
Inorganic Chemistry
chemistry.chemical_classification
chemistry.chemical_compound
Base (chemistry)
Chemistry
Stereochemistry
Organic Chemistry
Iminium
Lewis acids and bases
Physical and Theoretical Chemistry
Frustrated Lewis pair
Enamine
Adduct

Details

ISSN :
15206041 and 02767333
Volume :
32
Database :
OpenAIRE
Journal :
Organometallics
Accession number :
edsair.doi...........d23fc7f37964457155bf177ab0be459f
Full Text :
https://doi.org/10.1021/om4004225
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