Reductive coupling of butyryl chloride in the presence of CoCl(PPh3)3

Authors :: Maxim G. Vinogradov
G. I. Nikishin
A. B. Tuzikov
Source :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:773-775
Publication Year :: 1983
Publisher :: Springer Science and Business Media LLC, 1983.
Abstract: 1. Reductive coupling of butyryl chloride with CoCl(PPh3)3 affords 4-heptanone, 4,5-octanedione, 4-hydroxy-5-octanone, 4-butyryloxy-5-octanone, and 4,5-dibutyryloxy-4-octene. 2. A mechanism for the reductive coupling of butyryl chloride is proposed, involving the intermediate formation of an acylcobalt(III) dichloride complex.

Subjects :: Coupling (electronics)
chemistry.chemical_compound
Chemistry
medicine
Organic chemistry
General Chemistry
Butyryl chloride
Medicinal chemistry
Chloride
medicine.drug

ISSN :: 15739171 and 05685230
Volume :: 32
Database :: OpenAIRE
Journal :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :: edsair.doi...........d28912bca47b103be606931f42dd4c12
Full Text :: https://doi.org/10.1007/bf00953474