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ChemInform Abstract: NHC-Stabilized Gold(I) Complexes: Suitable Catalysts for 6-exo-dig Heterocyclization of 1-(o-Ethynylaryl)ureas

Authors :
Carmen Ramírez de Arellano
Ana Gimeno
Mercedes Medio-Simón
Gregorio Asensio
Ana B. Cuenca
Source :
ChemInform. 41
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

Under the optimized gold catalysis, the less favored and more challenging 6-exo-dig cyclized products are formed in yields up to 96% from ureas bearing a terminal alkyne at the ortho-position.

Details

ISSN :
09317597
Volume :
41
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........d2bbf7e4f07a0348cd0fc4ad44ce78ba
Full Text :
https://doi.org/10.1002/chin.201039164