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Characterization and potential utilization of extracts and pyrolyzates from Jasminum nudiflorum Lindl. Bark

Authors :
Haiping Gu
Jun Yang
Xiaochen Yue
Su Shiung Lam
Wanxi Peng
Shin Ying Foong
Source :
Journal of Analytical and Applied Pyrolysis. 155:105092
Publication Year :
2021
Publisher :
Elsevier BV, 2021.

Abstract

Utilization of lignocellulosic biomass is increasingly important. Jasminum nudiflorum Lindl. (JNL) is a widely cultivated landscape plant in China. To evaluate the chemical components, pyrolysis characteristics as well as the potential values of JNL bark for utilization, the components were extracted using methanol, ethanol, and benzene/ethanol (2:1, v/v) and pyrolyzed from room temperature to 300 °C, respectively. Many components were detected in the extracts and the pyrolyzates of JNL bark and their chemical properties were analyzed. The compounds identified in the extracts and the pyrolyzates of JNL bark included acids, aldehydes, alcohols, esters, ketones, aromatics, saccharides, olefins, and nitrogen-containing compounds. Some of the identified compounds, such as urs-12-en-28-al, 3-(acetyloxy)-, (3.beta.)-, 5-hydroxymethylfurfural, and vanillin, are widely used in the medical, energy, and food industries. The pyrolysis of JNL bark using thermogravimetric (TG) analyzer showed the highest reaction rate occurred at between 200 and 300 °C where the maximum mass loss was observed. According to the Coats-Redfern method, the calculated apparent activation energy (E) and pre-exponential factor (A) of the pyrolysis process of JNL bark were 52.04 kJ mol−1 and 3.14 × 105 min−1, respectively. This research provides information on the components and pyrolysis characteristics of JNL bark, which shows great potential for application in medical, food, and chemical industries.

Details

ISSN :
01652370
Volume :
155
Database :
OpenAIRE
Journal :
Journal of Analytical and Applied Pyrolysis
Accession number :
edsair.doi...........d37d9e752f7e012f0f7abce54e61e5cb
Full Text :
https://doi.org/10.1016/j.jaap.2021.105092