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Bio-fuel oil characteristic of rice bran wax pyrolysis
- Source :
- Renewable Energy. 119:193-202
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- The pyrolysis characteristic of rice bran wax (RBW) and its bio-fuel oil were analyzed. TG, Py-GC-MS, TG-MS, FTIR, 1H NMR and 13C NMR were all carried out to analysis RBW pyrolysis characteristic and bio-fuel oil characteristic. TG results showed that RBW pyrolysis temperature was mainly in the temperature range of 350 °C–450 °C. The mean activation energy values calculated from KAS method and FWO method was 106.15 kJ/mol and 115.72 kJ/mol, respectively. The TG-MS results showed that main gas products were alkane and olefins. The Py-GC-MS also found the mainly components of pyrolysis products were alkane and alkene. The 1H NMR, 13C NMR and FTIR experiments were also carried out to confirm the component of bio-fuel oil. The results found that the main components of pyrolysis products were alkane and alkene. The bio-fuel oil properties were also analyzed. The acid value was very low. It was about 10 mg(KOH)/g. And the coke was found. The yield was about 8%. According to above results, it was confirmed that RBW maybe was a good bio-resource to obtain long carbon chain bio-fuel oil.
- Subjects :
- chemistry.chemical_classification
Alkane
Acid value
Renewable Energy, Sustainability and the Environment
Alkene
020209 energy
02 engineering and technology
Coke
Carbon-13 NMR
chemistry
0202 electrical engineering, electronic engineering, information engineering
Proton NMR
Rice bran wax
Pyrolysis
Nuclear chemistry
Subjects
Details
- ISSN :
- 09601481
- Volume :
- 119
- Database :
- OpenAIRE
- Journal :
- Renewable Energy
- Accession number :
- edsair.doi...........d402e918dd84e2ec6958167ad195044a
- Full Text :
- https://doi.org/10.1016/j.renene.2017.12.012