Novel chain mechanism for the formyl-metal to hydrido-metal conversion. Free radical, photochemical and electrochemical methods of initiation

Authors :: C. P. Casey
Christian Amatore
B. A. Narayanan
Jay K. Kochi
Source :: Journal of the American Chemical Society. 105:6351-6352
Publication Year :: 1983
Publisher :: American Chemical Society (ACS), 1983.
Abstract: Etude cinetique de la conversion du complexe formyl HC(=O)re en complexe hydruro H(re) ou re=(OC) 5 ReRe(CO) 4 − Mecanisme: HC(=O)re+re • →OC(re) • +H(re), OC(re) • →CO+re •

Subjects :: Reaction mechanism
Chemistry
Photodissociation
General Chemistry
Photochemistry
Electrochemistry
Biochemistry
Catalysis
Metal
Colloid and Surface Chemistry
Chain (algebraic topology)
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Chain reaction

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