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Equation of state for Eu-doped SrSi2O2N2

Authors :
Ru-Shi Liu
Andrzej Suchocki
Marek Grinberg
J. Barzowska
Roman Minikayev
Stefan Carlson
Małgorzata Nowakowska
Olga Ermakova
Agata Kaminska
Guogang Li
Wojciech Paszkowicz
Karol Szczodrowski
Source :
The Journal of Chemical Physics. 141:014705
Publication Year :
2014
Publisher :
AIP Publishing, 2014.

Abstract

α-SrSi2O2N2 is one of the recently studied oxonitridosilicates applicable in optoelectronics, in particular in white LEDs. Its elastic properties remain unknown. A survey of literature shows that, up to now, nine oxonitridosilicate materials have been identified. For most of these compounds, doped with rare earths and manganese, a luminescence has been reported at a wavelength characteristic for the given material; all together cover a broad spectral range. The present study focuses on the elastic properties of one of these oxonitridosilicates, the Eu-doped triclinic α-SrSi2O2N2. High-pressure powder diffraction experiments are used in order to experimentally determine, for the first time, the equation of state of this compound. The in situ experiment was performed for pressures ranging up to 9.65 GPa, for Eu-doped α-SrSi2O2N2 sample mounted in a diamond anvil cell ascertaining the hydrostatic compression conditions. The obtained experimental variation of volume of the triclinic unit cell of α-SrSi2O2N2:Eu with rising pressure served for determination of the Birch-Murnaghan equation of state. The determined above quoted bulk modulus is 103(5) GPa, its first derivative is 4.5(1.1). The above quoted bulk modulus value is found to be comparable to that of earlier reported oxynitrides of different composition.

Details

ISSN :
10897690 and 00219606
Volume :
141
Database :
OpenAIRE
Journal :
The Journal of Chemical Physics
Accession number :
edsair.doi...........d6fb0cb02cc575123ca82d0326adb11e
Full Text :
https://doi.org/10.1063/1.4883502