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ChemInform Abstract: Straightforward Access to Methyl-polyheterocycles from Direct para-Lithiation of 3-Picoline

Authors :
Yves Fort
Julien Mathieu
Philippe C. Gros
Source :
ChemInform. 32
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

Various heterocycles have been introduced on the 3-picoline nucleus via a regioselective BuLi-Me2N(CH2)2OLi (BuLi-LiDMAE) mediated para-lithiation. Useful methyl-polyheterocycles were efficiently prepared by a one-pot lithiation–stannylation-Stille coupling sequence.

Details

ISSN :
15222667 and 09317597
Volume :
32
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........d72e908bdac05a715c403f08aacf0b78
Full Text :
https://doi.org/10.1002/chin.200123132