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Syntheses, crystal structures, and fluorescence of two complexes constructed by N ′-(pyridin-2-ylmethylene)-2-( 1H -1,2,4-triazol-1-yl)acetohydrazide
- Source :
- Journal of Coordination Chemistry. 63:4104-4112
- Publication Year :
- 2010
- Publisher :
- Informa UK Limited, 2010.
-
Abstract
- Two new binuclear complexes, Cd2(HL)2(NO3)4 · (CH3OH)2 (1) and Cu2(L)2(ClO4)2 (2), based on N′-(pyridin-2-ylmethylene)-2-(1H-1,2,4-triazol-1-yl)acetohydrazide (HL) and Cd(II) and Cu(II) salts have been synthesized and characterized by single crystal X-ray diffraction. Hydrogen bonds and π–π interactions extend both binuclear molecules, a 3-D supramolecular framework for 1 and 1-D staggered chains for 2. Fluorescence of both complexes is discussed.
Details
- ISSN :
- 10290389 and 00958972
- Volume :
- 63
- Database :
- OpenAIRE
- Journal :
- Journal of Coordination Chemistry
- Accession number :
- edsair.doi...........d74a91931f55d5a898f8878bbfcc4a2c