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Photochemical Reactions of Aryltriethylgermanes and Diethyldiphenylgermane

Authors :
Michio Kobayashi
Masanori Kobayashi
Source :
Bulletin of the Chemical Society of Japan. 59:2807-2810
Publication Year :
1986
Publisher :
The Chemical Society of Japan, 1986.

Abstract

Aryltriethylgermanes and diethyldiphenylgermane were found to split easily to generate germyl radicals by irradiation with a medium-pressure mercury lamp in hexane or cyclohexane. The germyl free radicals produced reacted with hydrocarbon radicals generated from the solvent by hydrogen abstraction either by recombination or by disproportionation.

Details

ISSN :
13480634 and 00092673
Volume :
59
Database :
OpenAIRE
Journal :
Bulletin of the Chemical Society of Japan
Accession number :
edsair.doi...........d7b20ea3249bfd180081f46ee768a4f3
Full Text :
https://doi.org/10.1246/bcsj.59.2807