Photoinduced electron transfer reactions. Evidence for two different radical cations of hexamethyl(Dewar benzene)

Authors :: H. D. Rioth
Marcia L. Manion Schilling
Krishnan Raghavachari
Source :: Journal of the American Chemical Society. 106:253-255
Publication Year :: 1984
Publisher :: American Chemical Society (ACS), 1984.
Abstract: Isomerisation de l'hexamethyl bicyclo [2.2.0] hexadiene-2,5(1) en hexamethylbenzene(2). En solvants polaires conversion de (1) en (2) avec rendements quantiques superieurs a l'unite. Mecanismes radicalaires. Mise en evidence de 2 cations radicalaires differents 2 B 2 et 2 A 1

Subjects :: Dewar benzene
Reaction mechanism
Bicyclic molecule
General Chemistry
Nuclear magnetic resonance spectroscopy
Photochemistry
Biochemistry
Catalysis
Photoinduced electron transfer
chemistry.chemical_compound
Electron transfer
Colloid and Surface Chemistry
chemistry
Isomerization
Acetophenone

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