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Synthesis and optical properties of (S)-Nobin

Authors :
A. N. Skvortsov
E. P. Studentsov
N. K. Skvortsov
O. V. Piskunova
Source :
Russian Journal of General Chemistry. 79:962-966
Publication Year :
2009
Publisher :
Pleiades Publishing Ltd, 2009.

Abstract

A preparative method of synthesis of optically pure S-2-amino-2′-hydroxy-1,1′-binaphthyl (S-Nobin), the precoursor in the synthesis of other asymmetric 1,1-binaphthyls applied as the ligands at the creation of the catalysts of asymmetric synthesis, is modified. The UV and CD spectra of this compound were studied in detail and essential dependence of spectral information on the solvent nature was shown.

Details

ISSN :
16083350 and 10703632
Volume :
79
Database :
OpenAIRE
Journal :
Russian Journal of General Chemistry
Accession number :
edsair.doi...........d80da00534cbfb7f8d401a0db624efb9
Full Text :
https://doi.org/10.1134/s1070363209050168