Back to Search
Start Over
Near-room temperature transesterification over bifunctional CunO-Bs/SBA-15 catalyst for biodiesel production
- Source :
- Renewable Energy. 170:1-11
- Publication Year :
- 2021
- Publisher :
- Elsevier BV, 2021.
-
Abstract
- The transesterification of triglycerides is a critical step in biodiesel production. In this work, by loading boron-doped copper oxides onto SBA-15 mesoporous molecular sieve, an acid-base bifunctional catalyst (i.e., CunO-Bs/SBA-15) was prepared and applied to triglyceride transesterification. Compared with pure copper, sodium or boron oxides-based catalysts, CunO-Bs/SBA-15 enabled a higher biodiesel yield (>97.5%) at near room temperature (i.e., 40 °C) in 120 min. The characterization results showed that after B doping, the CunO-Bs/SBA-15 catalyst contained highly-dispersed acid-base sites without blocking the channels of porous SBA-15 support, which had good catalytic performance. Finally, in-situ DRIFTS was used to reveal the catalytic mechanism of the acid-base bifunctional groups of the as-prepared CunO-Bs/SBA-15 during transesterification.
- Subjects :
- Biodiesel
Materials science
060102 archaeology
Renewable Energy, Sustainability and the Environment
020209 energy
06 humanities and the arts
02 engineering and technology
Transesterification
Molecular sieve
Bifunctional catalyst
Catalysis
chemistry.chemical_compound
chemistry
Biodiesel production
0202 electrical engineering, electronic engineering, information engineering
0601 history and archaeology
Mesoporous material
Bifunctional
Nuclear chemistry
Subjects
Details
- ISSN :
- 09601481
- Volume :
- 170
- Database :
- OpenAIRE
- Journal :
- Renewable Energy
- Accession number :
- edsair.doi...........d9650c7ed0bb883b30a4d11fcb46dcc7