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A Methano-Bridged Dehydro[24]annulenedione. A Highly Diatropic Dicationic 22π-Electron Species in D2SO4

Authors :
Kaori Asano
Hiroyuki Higuchi
Gaku Yamamoto
Juro Ojima
Source :
Chemistry Letters. 22:1829-1832
Publication Year :
1993
Publisher :
The Chemical Society of Japan, 1993.

Abstract

A methanodehydro[24]annulenedione with a 1,4-dichlorobutatriene moiety was synthesized. The compound formed a highly stable dicationic species in D2SO4, which showed the strongest diatropicity hitherto reported for 22π-electron aromatic systems.

Details

ISSN :
13480715 and 03667022
Volume :
22
Database :
OpenAIRE
Journal :
Chemistry Letters
Accession number :
edsair.doi...........dae25a3c85ad65835b48d62cf6aa7eb3
Full Text :
https://doi.org/10.1246/cl.1993.1829