Silver-catalyzed [4 + 3] cycloaddition of 1,3-dienes with alkenyl-N-triftosylhydrazones: a practical approach to 1,4-cycloheptadienes

A formal [4 + 3] cycloaddition of 1,3-dienes with alkenyl-N-triftosylhydrazones was developed using silver catalysis, producing a broad spectrum of complex 1,4-cycloheptadienes with high yields and predictable stereochemistry.