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Dialkylamido Sulfoxylic Acid Fluorides, I: Synthesis and Reactions with Olefins
- Source :
- Phosphorus, Sulfur, and Silicon and the Related Elements. 184:1149-1160
- Publication Year :
- 2009
- Publisher :
- Informa UK Limited, 2009.
-
Abstract
- The reaction of potassium fluoride with the corresponding acid chlorides results in the formation of dialkylamido sulfoxylic acid fluorides Alk 2 N-S-F. Stereo- and regioselectivity of dimethylamido and diisopropylamido sulfoxylic acid fluorides addition reactions to the C,C double bond in cyclohexene, 3,4-dihydro-2H-pyrane, and vinyl ethyl ether has been investigated. This reaction is a convenient approach to the β -fluoroalkyl sulfenic acid derivatives.
Details
- ISSN :
- 15635325 and 10426507
- Volume :
- 184
- Database :
- OpenAIRE
- Journal :
- Phosphorus, Sulfur, and Silicon and the Related Elements
- Accession number :
- edsair.doi...........db9a33e40a8de1bdecd4767d638c81cd
- Full Text :
- https://doi.org/10.1080/10426500902855182