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Bis[(diphenylphosphino)acetato-κ2O,P]palladium(II) dichloromethane solvate

Authors :
Fangfang Jian
Ren He
Hailian Xiao
Mengping Guo
Source :
Acta Crystallographica Section E Structure Reports Online. 61:m1635-m1636
Publication Year :
2005
Publisher :
International Union of Crystallography (IUCr), 2005.

Abstract

The title compound, [Pd(C14H12O2P)2]·CH2Cl2, consists of mononuclear [(Ph2PCH2COO)2Pd] complexes and dichloro­methane mol­ecules in a 1:1 molar ratio. The two (diphenyl­phosphino)acetate ligands are coordinated to the central Pd atom by their P and O atoms, forming five-membered chelate rings. The PdII atom has a distorted square-planar configuration [Pd—O = 2.076 (3) and 2.082 (3) A, and Pd—P = 2.214 (1) and 2.216 (1) A].

Details

ISSN :
16005368
Volume :
61
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........dca3841259588875a82eee9458be2b04