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Bis[(diphenylphosphino)acetato-κ2O,P]palladium(II) dichloromethane solvate
- Source :
- Acta Crystallographica Section E Structure Reports Online. 61:m1635-m1636
- Publication Year :
- 2005
- Publisher :
- International Union of Crystallography (IUCr), 2005.
-
Abstract
- The title compound, [Pd(C14H12O2P)2]·CH2Cl2, consists of mononuclear [(Ph2PCH2COO)2Pd] complexes and dichloro­methane mol­ecules in a 1:1 molar ratio. The two (diphenyl­phosphino)acetate ligands are coordinated to the central Pd atom by their P and O atoms, forming five-membered chelate rings. The PdII atom has a distorted square-planar configuration [Pd—O = 2.076 (3) and 2.082 (3) A, and Pd—P = 2.214 (1) and 2.216 (1) A].
Details
- ISSN :
- 16005368
- Volume :
- 61
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Structure Reports Online
- Accession number :
- edsair.doi...........dca3841259588875a82eee9458be2b04