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Stabilization by Configurational Entropy of the Cu(II) Active Site during CO Oxidation on Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O

Authors :
Piero Torelli
Paolo Ghigna
Umberto Anselmi Tamburini
Luca Braglia
Tommaso Pozzi
Valentina Colombo
Martina Fracchia
Source :
The Journal of Physical Chemistry Letters. 11:3589-3593
Publication Year :
2020
Publisher :
American Chemical Society (ACS), 2020.

Abstract

The mechanisms of CO oxidation on the Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O high-entropy oxide were studied by means of operando soft X-ray absorption spectroscopy. We found that Cu is the active metal and th...

Details

ISSN :
19487185
Volume :
11
Database :
OpenAIRE
Journal :
The Journal of Physical Chemistry Letters
Accession number :
edsair.doi...........de9e9756fd8dd0c69ee632ac3225589d
Full Text :
https://doi.org/10.1021/acs.jpclett.0c00602