Membrane reactors for hydrogenation and dehydrogenation processes based on supported palladium

Membrane reactors applied to catalytic reactions are currently being studied in many places world-wide. Significant developments in membrane science and the vision of process intensification by multifunctional reactors have stimulated a lot of academic and industrial research, which is impressively demonstrated by more than 100 scientific papers on catalytic membrane reactors being published per year. Palladium as a noble metal with exceptional hydrogen permeation properties and, at the same time, broad applicability as a catalyst, first of all for hydrogenation, is part of many of these developments. This paper discusses two different membrane reactor concepts which both rely on supported palladium, on the one hand as a permselective membrane material, and on the other hand as base component of a membrane-type hydrogenation catalyst. Dense palladium composite membranes can be used for hydrogen separation from packed-bed catalysts in gas-phase hydrocarbon dehydrogenation reactions. Mesoporous membranes containing dispersed bimetallic Pd/X-clusters can be employed as so-called catalytic diffusers for liquid-phase hydrogenation, e.g. of nitrate and nitrite in water. The principles of both concepts are introduced, recently obtained experimental data are evaluated in connection with literature results, and the perspectives for further development are highlighted.