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A dramatic solvent effect during aromatic halogen-metal exchanges. Different products from lithiation of polyfluorobromobenzenes in ether and tetrahydrofuran

Authors :
Thomas M. Stickney
William C. Patt
Alexander James Bridges
Source :
The Journal of Organic Chemistry. 55:773-775
Publication Year :
1990
Publisher :
American Chemical Society (ACS), 1990.

Abstract

La lithiation suivie d'une carboxylation du [bromo trifluoro] benzene conduit dans le THF a l'acide bromo trifluoro benzoique; dans l'ether d'ethyle l'acide trifluoro benzoique est obtenu

Details

ISSN :
15206904 and 00223263
Volume :
55
Database :
OpenAIRE
Journal :
The Journal of Organic Chemistry
Accession number :
edsair.doi...........e01cc310eb666957d8dde1197c908952
Full Text :
https://doi.org/10.1021/jo00289a069