Synthesis and characterization of 2,1,3-benzothiadiazole-thieno[3,2-b]thiophene-based charge transferred-type polymers for photovoltaic application

New low-band-gap copolymers, including thieno[3,2-b]thiophene and 2,1,3-benzothiadiazole, were synthesized as photovoltaic materials. Thiophene was introduced to provide extended π-conjugation length and charge transfer properties. A band gap ( E g op =1.62 eV, E g ec =1.51 eV) of this polymer was investigated through UV–vis spectroscopy and cyclic voltammetry. A bulk heterojunction structure of glass/indium tin oxide (ITO)/PEDOT:PSS/polymer-PCBM(1:3)/LiF/Al was fabricated for investigating photovoltaic properties. PC 71 BM was used as an acceptor material, due to its increased absorption in the visible region, in comparison with PC 61 BM. In this polymer, incident photon-to-current conversion efficiency (IPCE) was as high as 50%. Moreover, maximum power conversion efficiency (PCE) of up to 1.72% was achieved under AM 1.5 G conditions. It demonstrated relatively high V OC (0.67 V) and J SC (6.86 mA/cm 2 ), while a low fill factor value (0.37) was obtained.