Substituent effects in the rhodium-catalyzed hydroformylation of olefins using bis(diarylphosphino)methylamino ligands

Authors :: Manfred T. Reetz
Siegfried R. Waldvogel
Richard Goddard
Source :: Tetrahedron Letters. 38:5967-5970
Publication Year :: 1997
Publisher :: Elsevier BV, 1997.
Abstract: Rhodium-complexes of bis(diarylphosphino)methylamino ligands RN(CH2PPh2)2 are active catalysts in the hydroformylation of 1-octene and 2-vinylnaphthalene, regio-selectivity (n/iso-ratio) and catalyst activity (TOF) depending upon the nature of the parasubstituent in the N-aryl moiety (R = C6H5, p-CF3C6H4, p-NMe2C6H4).

Subjects :: chemistry.chemical_compound
chemistry
Organic Chemistry
Drug Discovery
Substituent
chemistry.chemical_element
Moiety
Biochemistry
Medicinal chemistry
Hydroformylation
Rhodium
Catalysis

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