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Robust superhydrophobic-superoleophilic polytetrafluoroethylene nanofibrous membrane for oil/water separation
- Source :
- Journal of Membrane Science. 540:354-361
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- A robust polytetrafluoroethylene (PTFE) nanofibrous membrane was prepared by a simple electrospinning-sintering strategy for efficient oil/water separation. Specifically, a PTFE@PVA hybrid nanofibrous membrane in which PTFE particles were uniformly distributed in PVA nanofiber was first prepared by electrospinning, then a sintering treatment was applied to obtain the PTFE nanofibrous membrane. Electron microscopic characterization revealed that the membrane was formed by a sintering mechanism of a fast decomposition of PVA followed by a slower fusion of PTFE particles. Spectroscopic characterization confirmed that the PVA polymer was completely decomposed after 8 h of sintering. The resulting membrane had a ratio of fluorine to carbon atomic ratio of 2.0, indicating that a pure PTFE nanofibrous membrane was obtained. The as-prepared PTFE membrane exhibited superhydrophobic property with a water contact angle of 155.0° and a sliding angle of 5.1°. Its tensile strength was as high as 19.7 MPa, indicating excellent mechanical strength. The membrane was successfully applied for gravity-driven oil/water separation with a permeate flux of 1215 L m−2 h−1. Moreover, its excellent corrosion resistance and mechanical stability suggest that the PTFE nanofibrous membrane could stand harsh environment existing in industrial oil/water separation processes.
- Subjects :
- chemistry.chemical_classification
Polytetrafluoroethylene
Materials science
Filtration and Separation
02 engineering and technology
Polymer
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Biochemistry
Electrospinning
0104 chemical sciences
Contact angle
chemistry.chemical_compound
Membrane
chemistry
Chemical engineering
Nanofiber
Ultimate tensile strength
Polymer chemistry
General Materials Science
Atomic ratio
Physical and Theoretical Chemistry
0210 nano-technology
Subjects
Details
- ISSN :
- 03767388
- Volume :
- 540
- Database :
- OpenAIRE
- Journal :
- Journal of Membrane Science
- Accession number :
- edsair.doi...........e4ac1d4c285f17b7a04175e0a7b4e78f