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Cation binding by 21,31-diphenyl-l 2,42-dioxo-7,10,13-trioxa-1,4(3,1)-diquinoxalina-2 (2,3),3(3,2)-diindolizinacyclopentadecaphane and its acyclic analog

Authors :
Vakhid A. Mamedov
V. V. Yanilkin
Natalya V. Nastapova
Alexey S. Stepanov
A. A. Kalinin
Source :
Russian Chemical Bulletin. 58:89-94
Publication Year :
2009
Publisher :
Springer Science and Business Media LLC, 2009.

Abstract

The binding of cations Li+, Na+, K+, Cs+, Ag+, Zn2+, Ni2+, Co2+, NH4 + (group I), H+, Mg2+, Al3+, Ga3+ (group II), and Ca2+, Pb2+ (group III) by 21,31-diphenyl-l 2,42-dioxo- 7,10,13-trioxa-l,4(3,1)-diquinoxalina-2(2,3),3(3,2)-diindolizinacyclopentadecaphane (1), which contains two indolizine and two quinoxaline fragments and 3,6,9-trioxaundecanes spacer, and by its acyclic analog (2) was studied using cyclic voltammetry in MeCN/0.1 M Bu4NBF4. It was concluded that the ions of group I are not bound by these compounds, the ions of group II exhibit the reversible redox-switched binding by the carbamoyl groups of the quinoxaline fragments, whereas the ions of group III are bound not only by the initial compounds and radical cations 1 and 2, but also by dication 1. This binding of the Ca2+ and Pb2+ ions stabilizes dication 1.

Details

ISSN :
15739171 and 10665285
Volume :
58
Database :
OpenAIRE
Journal :
Russian Chemical Bulletin
Accession number :
edsair.doi...........e51be2c08621116427eefda688085de6
Full Text :
https://doi.org/10.1007/s11172-009-0013-7