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Stereocomplexation kinetics of enantiomeric poly(<scp>l</scp>-lactide)/poly(<scp>d</scp>-lactide) blends seeded by nanocrystalline cellulose

Authors :
Pei Lv
Huiyu Bai
Weifu Dong
Piming Ma
Mingqing Chen
Long Jiang
Source :
RSC Advances. 5:71115-71119
Publication Year :
2015
Publisher :
Royal Society of Chemistry (RSC), 2015.

Abstract

Stereocomplexation of poly(lactide) was significantly promoted by seeding with nanocrystal cellulose (NCC). A NCC-accelerated and time-dependent stereocomplex crystal (SC) growth are discovered. Moreover, SC-crystallization regime transitions (II–III) were identified and both the nucleation constant (Kg) and transition temperature (Ttr) were strongly increased in the presence of the NCC.

Details

ISSN :
20462069
Volume :
5
Database :
OpenAIRE
Journal :
RSC Advances
Accession number :
edsair.doi...........e592051e6739feae49a7d97dc471debe
Full Text :
https://doi.org/10.1039/c5ra12586c