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Stabilization of the blue phases of simple rodlike monoester compounds by addition of their achiral homologues
- Source :
- Journal of Materials Chemistry. 22:8484
- Publication Year :
- 2012
- Publisher :
- Royal Society of Chemistry (RSC), 2012.
-
Abstract
- As novel rodlike liquid crystalline ester compounds exhibiting blue phases (BPs), chiral 4-(4′-alkoxyphenyl)phenyl 4-(4′-alkoxyphenyl)benzoate derivatives (R–C6H4–C6H4–OCO–C6H4–C6H4–R′), 1 (R = R′ = (R)-1-methylheptyloxy, BP range: 1.6 K on heating), 2 (R = (R)-1-methylheptyloxy, R′ = n-octyloxy, BP range: 0.8 K on heating), 4 (R = (R)-1-methylheptyloxy, R′ = H, BP range: 1.0 K on heating), were synthesized and their phase behaviors were investigated. Further, the BP of 1 was stabilized by addition of its achiral homologue ester compound 3 (R = R′ = n-octyloxy). In the range of the composite ratio of 1 : 3 from 10 : 0 to 0 : 10, the BP temperature range became wider with increase of the content of 3 in the mixture. At the ratio of 6 : 4, the BP indicated the widest temperature range in the mixing experiment (5.0 K on heating and 6.0 K on cooling).
Details
- ISSN :
- 13645501 and 09599428
- Volume :
- 22
- Database :
- OpenAIRE
- Journal :
- Journal of Materials Chemistry
- Accession number :
- edsair.doi...........e5cdfa7199d2fa81d2abce9e5f798652