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Isomers in fac-[ReBr(CO)3( Lc)2](Lc=cis-3,4-dihydro-2,3,4,5-tetraphenyl-2H-1,2,3-diazaphosphole) arising from chirality of phosphorus ligands: separation and X-ray structural studies
- Source :
- Journal of the Chemical Society, Dalton Transactions. :21
- Publication Year :
- 1987
- Publisher :
- Royal Society of Chemistry (RSC), 1987.
-
Abstract
- Reaction of cis-[ReBr(CO)4( Lc)] with chiral Lc(cis-3,4-dihydro-2,3,4,5-tetraphenyl-2H-1,2,3-diazaphosphole) afforded fac-[ReBr(CO)3(Lc)2] which, owing to the racemic nature of Lc(R,S-L), should be a mixture of three predictable diastereoisomers: fac-[ReBr(CO)3(R-L)(S-L)][meso-(A) or meso-(B)] and the enantiomeric pair fac-[ ReBr(CO)3(R,S-L)2]. Two of these forms, meso-(A) and the enantiomeric pair, have been separated by column chromatography and their nature unambiguously attributed by X-ray studies. fac-[ReBr(CO)3(R-L)(S-L)] crystallizes in the monoclinic space group P21/n, with a= 19.481(4), b= 13.204(3), c= 20.083(8)A, β= 110.56(3)°, and Z= 4; R′= 0.046. fac-[ReBr(CO)3(R,S-L)2]·C6H14·C7H16 crystallizes in the monoclinic space group P21/n, with a= 12.191(3), b= 20.939(4), c= 21.713(5)A, β= 93.93(3)°, and Z= 4; R′= 0.048. Attempts to separate or detect spectroscopically isomers of fac-[ReBr( CO)3( L)2](L = racemic PMeEtPh) failed, indicating that interligand interactions are the determining factors in achieving the separation.
Details
- ISSN :
- 13645447 and 03009246
- Database :
- OpenAIRE
- Journal :
- Journal of the Chemical Society, Dalton Transactions
- Accession number :
- edsair.doi...........e65f1f2f6d00387608e7cd5f017c5e5c
- Full Text :
- https://doi.org/10.1039/dt9870000021