A Bowl-Shaped Phosphine as a Ligand in Rhodium-Catalyzed Hydrosilylation: Rate Enhancement by a Mono(phosphine) Rhodium Species

Authors :: Yasushi Tsuji
Naoki Sawada
Yasushi Obora
Tetsuo Iwasawa
Makoto Tokunaga
Osamu Niyomura
Source :: Organometallics. 24:3468-3475
Publication Year :: 2005
Publisher :: American Chemical Society (ACS), 2005.
Abstract: Bowl-shaped phosphine (BSP) ligands markedly accelerated the rhodium-catalyzed hydrosilylation of ketones and ketimines as compared with the effect of conventional phosphine ligands such as PPh3 an...

Subjects :: Inorganic Chemistry
chemistry.chemical_compound
Chemistry
Hydrosilylation
Ligand
Organic Chemistry
Polymer chemistry
Organic chemistry
chemistry.chemical_element
Physical and Theoretical Chemistry
Phosphine
Rhodium
Catalysis

Full Text Access

Tools