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Influence of low-frequency vibrations on the chemical reaction rate in the liquid phase for reagent association

Authors :
Z. S. Andrianova
L. P. Smirnov
T. P. Kulagina
Source :
Russian Chemical Bulletin. 66:30-33
Publication Year :
2017
Publisher :
Springer Science and Business Media LLC, 2017.

Abstract

A bistable state of a reaction system was theoretically shown to be possible for a multistage chemical reaction in the case of reagent association. The conditions for the bistability origin with a possible substantial change in the rate of reaction product formation were determined. The conditions for the appearance of oscillations of intermediate concentrations and the possibility for the origination of the corresponding acoustic frequencies were studied. The action of external vibrations with the frequency coinciding with that of intrinsic intermediate concentration oscillations can increase the reaction rate of reaction product formation.

Details

ISSN :
15739171 and 10665285
Volume :
66
Database :
OpenAIRE
Journal :
Russian Chemical Bulletin
Accession number :
edsair.doi...........e8d1684c688ed3f52a17520c7e527b51
Full Text :
https://doi.org/10.1007/s11172-017-1695-x