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Influence of low-frequency vibrations on the chemical reaction rate in the liquid phase for reagent association
- Source :
- Russian Chemical Bulletin. 66:30-33
- Publication Year :
- 2017
- Publisher :
- Springer Science and Business Media LLC, 2017.
-
Abstract
- A bistable state of a reaction system was theoretically shown to be possible for a multistage chemical reaction in the case of reagent association. The conditions for the bistability origin with a possible substantial change in the rate of reaction product formation were determined. The conditions for the appearance of oscillations of intermediate concentrations and the possibility for the origination of the corresponding acoustic frequencies were studied. The action of external vibrations with the frequency coinciding with that of intrinsic intermediate concentration oscillations can increase the reaction rate of reaction product formation.
- Subjects :
- Bistability
Chemistry
Low frequency vibration
Liquid phase
02 engineering and technology
General Chemistry
010402 general chemistry
Photochemistry
01 natural sciences
Chemical reaction
0104 chemical sciences
Vibration
Reaction rate
Chemical kinetics
020303 mechanical engineering & transports
0203 mechanical engineering
Chemical physics
Reagent
Nuclear Experiment
Subjects
Details
- ISSN :
- 15739171 and 10665285
- Volume :
- 66
- Database :
- OpenAIRE
- Journal :
- Russian Chemical Bulletin
- Accession number :
- edsair.doi...........e8d1684c688ed3f52a17520c7e527b51
- Full Text :
- https://doi.org/10.1007/s11172-017-1695-x