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Can the equilibrium interfacial tensions be more in magnitude than non-equilibrium ones? Comment on 'Electrocapillarity and zero-frequency differential capacitance at the interface between mercury and ionic liquids measured using the pendant drop method' by N. Nishi et al. [Phys. Chem. Chem. Phys., 2015, 17, 5219]

Authors :
Rouvim Kadis
Source :
Chemical Physics. 516:175-176
Publication Year :
2019
Publisher :
Elsevier BV, 2019.

Abstract

In the paper commented upon, the electrocapillary curves for mercury in ionic liquids, obtained by static (pendant drop) and dynamic (drop-time) measurement methods, were compared to support the inference about ultraslow relaxation at the interface. Yet, the static, i.e. equilibrium interfacial tensions proved to be more in magnitude (at E

Details

ISSN :
03010104
Volume :
516
Database :
OpenAIRE
Journal :
Chemical Physics
Accession number :
edsair.doi...........e917ad94de92cb830aebeca2d22d76d7
Full Text :
https://doi.org/10.1016/j.chemphys.2018.09.007