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Can the equilibrium interfacial tensions be more in magnitude than non-equilibrium ones? Comment on 'Electrocapillarity and zero-frequency differential capacitance at the interface between mercury and ionic liquids measured using the pendant drop method' by N. Nishi et al. [Phys. Chem. Chem. Phys., 2015, 17, 5219]
- Source :
- Chemical Physics. 516:175-176
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- In the paper commented upon, the electrocapillary curves for mercury in ionic liquids, obtained by static (pendant drop) and dynamic (drop-time) measurement methods, were compared to support the inference about ultraslow relaxation at the interface. Yet, the static, i.e. equilibrium interfacial tensions proved to be more in magnitude (at E
- Subjects :
- Measurement method
010304 chemical physics
Differential capacitance
Drop (liquid)
General Physics and Astronomy
Electrocapillarity
chemistry.chemical_element
Thermodynamics
010402 general chemistry
01 natural sciences
0104 chemical sciences
Mercury (element)
Physics::Fluid Dynamics
Drop method
chemistry.chemical_compound
chemistry
0103 physical sciences
Ionic liquid
Physical and Theoretical Chemistry
Zero frequency
Subjects
Details
- ISSN :
- 03010104
- Volume :
- 516
- Database :
- OpenAIRE
- Journal :
- Chemical Physics
- Accession number :
- edsair.doi...........e917ad94de92cb830aebeca2d22d76d7
- Full Text :
- https://doi.org/10.1016/j.chemphys.2018.09.007